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2-溴甲基丙烯酸甲酯

2-溴甲基丙烯酸甲酯名称

[ CAS 号 ]:
4224-69-5

[ 中文名 ]:
2-(溴甲基)丙烯酸甲酯

[ 英文名 ]:
Methyl 2-(bromomethyl)acrylate

[中文别名 ]:

2-溴甲基丙烯酸甲酯

[英文别名 ]:

Methyl 2-(bromomethyl)acrylate
2-(Bromomethyl)acrylic Acid Methyl Ester
methyl 2-(bromomethyl)prop-2-enoate
2-Propenoic acid, 2-(bromomethyl)-, methyl ester
MFCD00011697

2-溴甲基丙烯酸甲酯物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
187.1±0.0 °C at 760 mmHg

[ 分子式 ]:
C₅H₇BrO₂

[ 分子量 ]:
179.012

[ 闪点 ]:
78.3±0.0 °C

[ 精确质量 ]:
177.962936

[ PSA ]:
26.30000

[ LogP ]:
1.88

[ 外观性状 ]:
透明无色至略黄色液体

[ 蒸汽压 ]:
0.6±0.3 mmHg at 25°C

[ 折射率 ]:
1.471

[ 储存条件 ]:
2-8°C

2-溴甲基丙烯酸甲酯MSDS

2-溴甲基丙烯酸甲酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AS4900000

CHEMICAL NAME :: Acrylic acid, 2-(bromomethyl)-, methyl ester

CAS REGISTRY NUMBER :: 4224-69-5

LAST UPDATED :: 199710

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C5-H7-Br-O2

MOLECULAR WEIGHT :: 179.03

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-1090-1048S

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2-溴甲基丙烯酸甲酯安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H315-H318-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
UN 2810 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
AS4900000

[ 海关编码 ]:
2916190090

2-溴甲基丙烯酸甲酯合成路线

2-溴甲基丙烯酸甲酯海关

[ 海关编码 ]: 2916190090

[ 中文概述 ]:
2916190090 其他不饱和无环一元羧酸（包括其酸酐、酰卤化物，过氧化物和过氧酸以及它们的衍生物）。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

2-溴甲基丙烯酸甲酯文献

Structure-activity relationships of tulipalines, tuliposides, and related compounds as inhibitors of MurA.

Bioorg. Med. Chem. Lett. 20 , 5757-62, (2010)

The enzyme MurA performs an essential step in peptidoglycan biosynthesis and is therefore a target for the discovery of novel antibacterial compounds. We report here the inhibition of MurA by natural ...

Diastereocontrolled synthesis of enantioenriched 3,4-disubstituted beta-prolines.

J. Org. Chem. 72 , 398, (2007)

Enantioenriched 3,4-disubstituted beta-prolines have been prepared with a high diastereocontrol through a carbometalation reaction or through a domino Michael addition/carbometalation reaction.

Use of methyl 2-(bromomethyl) acrylate as a chain-transfer agent to yield functionalized macromonomers via conventional and living radical polymerizations. Bon, SAF, et al.

Macromolecules 33(16) , 5819-5824, (2000)

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