Aromatization Studies. VI. Aminobiphenyls and Naphthylamines

EC Horning, MG Horning, EJ Platt

文献索引：Horning; Horning; Platt Journal of the American Chemical Society, 1948 , vol. 70, p. 288

全文：HTML全文

被引用次数: 1

摘要

Summary 2-Thienylsodium has been. prepared in yields of 60-89'70 from an alkyl or aryl halide, sodium amalgam, and thiophene, and in yields of 84% from 2-chlorothiophene and sodium amalgam. 2-Chloro-, 2-bromo-and 2-iodothiophenes have been metalated with sodium without replacement of the halo-atom, and the 5-halo-2-thienyl sodium compounds so formed were carbonated to give 2-chloro-, 5-bromo-and 5-iodo-2-thiophenecarbox-ylic ...