Metal??Free Synthesis of Imido Derivatives by Direct Oxidation of α??Amido Sulfones

F Martinelli, A Palmieri, M Petrini

文献索引：Martinelli, Fabio; Palmieri, Alessandro; Petrini, Marino European Journal of Organic Chemistry, 2010 , # 26 p. 5085 - 5089

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被引用次数: 3

摘要

Abstract Oxidation of α-amidoaryl sulfones with m-chloroperoxybenzoic acid under mild conditions readily provides the corresponding imides in satisfactory yields. The overall process probably involves formation of an N-acyliminium ion intermediate, which by attack of the peroxyacid anion generates the final imido derivatives.