Inorganic Chemistry

Oxidative alkylation of cobalt complexes with hydrazines

EG Samsel, JK Kochi

文献索引：Samsel, E. G.; Kochi, J. K. Inorganic Chemistry, 1986 , vol. 25, p. 2450 - 2457

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被引用次数: 17

摘要

Summary In contrast to the behavior of binary sulfur-nitrogen ring systems, the six- mewbered 1, 2, 4, 6-thiatriazine unit is stable to both oxidation and reduction. Examples of the three oxidation states-cation, neutral radical, and anion (in its protonated form)-have been structurally characterized. The structural and energetic differences between the different oxidation states can be understood in terms of the degree of occupation of the? r ...