Vapor-phase thermolyses of 3-hydroxy-1, 5-hexadienes. II. Effects of methyl substitution

A Viola, EJ Iorio, KKN Chen, GM Glover…

文献索引：Viola,A. et al. Journal of the American Chemical Society, 1967 , vol. 89, p. 3462 - 3470

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被引用次数: 59

摘要

Abstract: The vapor-phase thermolyses of 3-hydroxy-l, 5-hexadienes result in rearrangement to A5-unsaturated carbonyl compounds and in the formation of cleavage products. Based on a series of ten methyl-substituted compounds studied, the formation of these products is interpreted on the basis of two competing concerted bond reorganizations both of which proceed through a cyclic six-membered transition state. Production of cleavage products ...