Ritter Reactions between Alcohols and Acetonitrile Mediated by the Conducting Polymer Poly-(3, 4-ethylenedioxy Thiophene)(PEDOT)

JG D'Angelo, JA Cody, C Larrabee…

文献索引：D-Angelo, John G.; Cody, Jeremy A.; Larrabee, Christian; Ostrander, Danica J.; Rugg, Kyle W.; Mamangun, Donna Synthetic Communications, 2013 , vol. 43, # 23 p. 3224 - 3232

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摘要

Herein, we report new reactivity of the conducting polymer, poly-(3,4-ethylenedioxy thiophene) (PEDOT), where PEDOT mediates a Ritter reaction between alcohols and acetonitrile. The yields were variable and in most cases competitive with results obtained using sulfuric acid. Attempts at a stoichiometric reaction between benzonitrile and diphenylmethanol are also reported herein. Finally, described here are preliminary mechanistic studies that ...