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Dissociation of substituted benzenesulphonamides in water, methanol and ethanol

M Ludwig, O Pytela, K Kalfus…

文献索引:Ludwig, Miroslav; Pytela, Oldrich; Kalfus, Karel; Vecera, Miroslav Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 5 p. 1182 - 1192

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被引用次数: 21

摘要

Abstract Thirteen monosubstituted arylsulphonamides (XC 6 H 4 SO 2 NH 2) and two 3, 4- disubstituted arylsulphonamides (X 2 C 6 H 3 SO 2 NH 2) have been synthetized and their dissociation constants have been measured by potentiometric titration in water, methanol, and ethanol. The Hammett substitution dependences have been calculated for all the media, and changes in the reaction constants due to transition from water to alcohols are ...