Reactions of (9-anthryl) arylmethyl chloride and its homologs with nucleophiles under solvolytic conditions. Notable effects of reaction conditions and substituents on …

…, M Takagi, M Nojima, S Kusabayashi

文献索引：Ogata, Fujimaro; Takagi, Masato; Nojima, Masatomo; Kusabayashi, Shigekazu Journal of the American Chemical Society, 1981 , vol. 103, # 5 p. 1145 - 1153

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被引用次数: 16

摘要

Abstract: The reactions of (9-anthry1) arylmethyl chlorides 2a-e (the substituents are p-MeO, p-Me, H, p-Cl, and m-CI), the corresponding bromides 3b-d (the substituents are p-Me, H, and p-Cl), and the antimonate salts 4b-e (the substituents are pMe, H, pC1, and m-C1) with several nucleophiles have been examined. When 2 was allowed to react with sodium ethoxide, ethanol in the presence of triethylamine, sodium azide in aqueous DMF, and ...