2-(4-Pyridyl) ethyl as a protective group for sulfur functionality

AR Katritzky, I Takahashi…

文献索引：Katritzky, Alan R.; Takahashi, Ichiro; Marson, Charles M. Journal of Organic Chemistry, 1986 , vol. 51, # 25 p. 4914 - 4920

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被引用次数: 39

摘要

2-(4-Pyridyl) ethyl sulfides have been prepared from a variety of alkyl and aryl thiols and from alkyl and acyl halides. These sulfides and their corresponding sulfoxides and sulfones were each depyridylethylated by quaternization and subsequent treatment with mild base t.~ give respectively the thiols, sulfenic acids, sulfinic acids, and sulfenamides. During one of these protection-deprotection sequences, methyl 1-octyl sulfoxide was readily converted ...