Rearrangements of Polyynes. VII. 1 Formation of Allenes

JH Ford, CD Thompson, CS Marvel

文献索引：Ford; Thompson; Marvel Journal of the American Chemical Society, 1935 , vol. 57, p. 2619,2621

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被引用次数: 1

摘要

TI in which R'is a phenyl group and R and R" are t-butyl groups. Some interesting rearrangements were observed in the reactions which were used in the synthesis of the desired ethane and these seem to offer some clues as to the nature of the rearrangements of the polyynes themselves. Phenyl-t-butyl-t-butylethynylbromomethane (111) was synt. hesized by the series of reactions