Aryl shifts from silicon to carbon via. gamma.-and. delta.-silyl radicals

JW Wilt, WK Chwang, CF Dockus…

文献索引：Wilt,J.W. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 5534 - 5540

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被引用次数: 25

摘要

Abstract: A series of 12 y-and 6-halosilanes was prepared and characterized. Reduction of these halides at 140 OC with di-tertbutyl peroxide as the initiator led to the formation of rearranged as well as unrearranged products, all of which were separately synthesized for authentic comparison. The rearranged products arose from 1, 4-or 1, 5-aryl shifts from silicon to carbon and are the first such rearrangements to be reported. These shifts proceed via ...