Tetrahedron

Palladium complexes of phosphorus acid disubstituted ethers. synthesis, structure, catalysis

EE Nifant'ev, TS Kukhareva, MY Antipin, YT Struchkov…

文献索引：Nifant'ev, E. E.; Kukhareva, T. S.; Antipin, M. Yu.; Struchkov, Yu. T.; Klabunovsky, E. I. Tetrahedron, 1983 , vol. 39, # 5 p. 797 - 803

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被引用次数: 10

摘要

Complexes of the type of [Pd2Cl2L4] have been prepared by the reaction of bis-(π- allylpalladium-chloride) with phosphorous acid disubstituted ethers; their structure has been studied by IR-and NMR-spectroscopy and X-ray analysis. The complexes have a dimeric centro-symmetric structure which is usual for bivalent palladium compounds with a slightly distorted flat-square coordination of the central atom. These compounds are active ...