Peroxide-induced α-elimination of organic halides from organotellurium (IV) halides

S Uemura, SI Fukuzawa

文献索引：Uemura, Sakae; Fukuzawa, Shin-ichi Journal of the Chemical Society, Chemical Communications, 1980 , # 21 p. 1033 - 1034

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摘要

Summary Treatment of organotellurium(1v) halides with t-butyl hydroperoxide in 1,4-dioxan, acetic acid, or acetonitrile affords the corresponding organic halides in good to moderate yields presumably as the result of a 1,2-halogen shift. ... THE well established p-elimination giving olefins from organoseleniuni(I1) compounds by oxidationf does not pro- ceed well with organotellurium(I1) compounds.2 In the latter case some alcohols are formed, ...