Kinetics of acyl migration in monoglycerides and dependence on acyl chainlength

G Boswinkel, JTP Derksen, K Van't Riet…

文献索引：Boswinkel; Derksen; Van't Riet; Cuperus JAOCS, Journal of the American Oil Chemists' Society, 1996 , vol. 73, # 6 p. 707 - 711

全文：HTML全文

被引用次数: 56

摘要

Abstract The chemical rearrangement reaction of β-into α-monoglycerides is described. Four monoglycerides with different fatty acid chainlength have been investigated, and the equilibrium constant and the reaction velocity constants characterizing the reaction of the chemical rearrangement were estimated with a mathematical model. A 1∶ 6.5 mixture of α/β- monoglycerides appeared to rearrage to a mixture of 1∶ 1 α/β-monoglycerides within 24 ...