Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-µ-peroxodisulfate (2–) ion in aqueous medium. A model for alkane oxidation through the …

M Lin, A Sen

文献索引：Lin, Minren; Sen, Ayusman Journal of the Chemical Society, Chemical Communications, 1992 , # 12 p. 892 - 893

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被引用次数: 59

摘要

In aqueous medium, at 105–115° C, SO4-˙(generated from S2O82–) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids.