Microwave specific Wolff rearrangement of α-diazoketones and its relevance to the nonthermal and thermal effect

…, SK Date, SP Chavan, HR Sonawane

文献索引：Sudrik; Nanjundiah; Sonawane Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1997 , vol. 36, # 12 p. 1103 - 1112

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被引用次数: 50

摘要

α-Diazoketones possess high electric dipole moments, as a consequence of the dipolar nature of the diazocarbonyl functional group. The vectorial analysis, theoretical calculations (PM3 and ab initio), and literature reports based on experimental and theoretical