A Novel One??Pot Conversion of Allyl Alcohols into Primary Allyl Halides Mediated by Acetyl Halide

N Kishali, MF Polat, R Altundas…

文献索引：Kishali, Nurhan; Polat, M. Fatih; Altundas, Ramazan; Kara, Yunus Helvetica Chimica Acta, 2008 , vol. 91, # 1 p. 67 - 72

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被引用次数: 6

摘要

Abstract A new and simple method for the synthesis of the primary allyl chlorides and bromides 9–16 from the secondary or tertiary allyl alcohols 3–8 and acyl halide was developed (Scheme 2, Table 1). Non-commercially available secondary and tertiary allyl alcohols were synthesized from the related ketones and aldehydes via the addition of vinylmagnesium chloride. Mechanistic studies indicate that the alcohols were first ...