Photochemical synthesis and properties of axially chiral naphthylpyridines

P Wessig, C Pick

文献索引：Wessig, Pablo; Pick, Charlotte Journal of Photochemistry and Photobiology A: Chemistry, 2011 , vol. 222, # 1 p. 263 - 265

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被引用次数: 8

摘要

Five alkynyl pyridines were prepared and cyclized to naphthylpyridines as the main products in the course of a Photo-Dehydro-Diels-Alder reaction. Four of the final products are axially chiral and the determination of the rotational barrier by DFT calculations, dynamic NMR and HPLC experiments is demonstrated.