Copper catalyzed ipso-nitration of iodoarenes, bromoarenes and heterocyclic haloarenes under ligand-free conditions

…, S Priyadarshini, ML Kantam, H Maheswaran

文献索引：Amal Joseph; Priyadarshini; Lakshmi Kantam; Maheswaran Tetrahedron Letters, 2012 , vol. 53, # 12 p. 1511 - 1513

被引用次数: 3

摘要

A catalytic protocol for the conversion of haloarenes into the corresponding nitroarenes is presented using copper salts under ligand-free conditions. The method was effectively utilized for the ipso-nitration of a broad variety of haloarenes that includes iodoarenes, bromoarenes, and heterocyclic haloarenes.

107623-21-2

1-苄氧基-3-碘苯

~79%

24318-00-1

1-(苄氧基)-3-硝基苯

~44%

~53%

~76%

~74%

~80%

~84%

~70%

~63%

~61%

~73%

~47%

~72%

~54%

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