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Hydrophosphinylation of unactivated terminal alkenes catalyzed by nickel chloride

S Ortial, HC Fisher, JL Montchamp

文献索引:Ortial, Stephanie; Fisher, Henry C.; Montchamp, Jean-Luc Journal of Organic Chemistry, 2013 , vol. 78, # 13 p. 6599 - 6608

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被引用次数: 23

摘要

The room-temperature hydrophosphinylation of unactivated monosubstituted alkenes using phosphinates (ROP (O) H2) and catalytic NiCl2 in the presence of dppe is described. The method is competitive with prior palladium-catalyzed reactions and uses a much cheaper catalyst and simple conditions. The scope of the reaction is quite broad in terms of unactivated terminal olefins, proceeds at room temperature, often avoids chromatographic ...