Acid??Free Synthesis of Carbazoles and Carbazolequinones by Intramolecular Pd??Catalyzed, Microwave??Assisted Oxidative Biaryl Coupling Reactions–Efficient …

…, MA Martin, JC Menendez

文献索引：Sridharan, Vellaisamy; Antonia Martin; Carlos Menendez European Journal of Organic Chemistry, 2009 , # 27 p. 4614 - 4621

全文：HTML全文

被引用次数: 39

摘要

Abstract A mild and efficient methodology for the synthesis of oxygenated carbazoles from diarylamines under non-acidic conditions was developed, based on a palladium-catalyzed, microwave-assisted double C–H bond activation process. This new protocol was successfully applied to the synthesis of three naturally occurring carbazoles, namely murrayafoline A, 2-methoxy-3-methylcarbazole, and glycozolidine. The scope of the ...