Abstract Two methods for synthesizing tertiary F-alkylated amines are reported. The more general method allows the access in 56–87% yields to various N, N-dialkyl F-alkyl amines. These amines are key intermediates leading in 52–96% yields to several families of surfactants, including zwitterionic and cationic derivatives and amine oxides, potentially useful in the formulation of fluorocarbon emulsions for diagnostic and therapeutic uses. ...
