Bio-organometallic Organosulfur Chemistry. Transi-tion Metal-Catalyzed Cross-Coupling Using Coen-zyme M or Thioglycolic Acid as the Leaving Group

…, W Liu, D Marshall, LS Liebeskind

文献索引：Srogl, Jiri; Liu, Wansheng; Marshall, Daniel; Liebeskind, Lanny S. Journal of the American Chemical Society, 1999 , vol. 121, # 40 p. 9449 - 9450

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被引用次数: 79

摘要

Metal-thiol and-thiolate interactions occur commonly and are of seminal importance in the biochemistry of life-sustaining processes. 1 Given the stability of the bond between a mercaptide ligand and various redox-active metals, it is of interest that Nature has evolved significant metalloenzymatic processes, which use key interactions of sulfur-containing functionalities with metals such as Ni, Co, Cu, and Fe (methanogenesis, 2 acetyl CoA ...