Tetrahedron

Light-mediated transformations of olefins into alcohols: reactions of hydroxyl radicals with cycloalkenes

HR Sonawane, BS Nanjundiah, RG Kelkar

文献索引：Sonawane, H. R.; Nanjundiah, B. S.; Kelkar, R. G. Tetrahedron, 1986 , vol. 42, # 24 p. 6673 - 6682

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被引用次数: 5

摘要

Reactions of hydroxyl radicals, generated by photodecomposition of hydrogen peroxide in acetonitrile, with a wide variety of cycloalkenes have been examined. The results show that the major reaction is the addition of hydroxyl radicals to the less substituted end of the double bond, furnishing the secondary alcohols. The reactivity pattern and the observed regio-and stereoselectivity clearly reveal that the steric parameters associated with the ...