Synthesis and Stable??Ion Studies of Regioisomeric Acetylnitropyrenes and Nitropyrenyl Carbinols and GIAO??DFT Study of Nitro Substituent Effects on α??Pyrenyl …

…, MA Arrica, T Okazaki, SD Bunge

文献索引：Laali, Kenneth K.; Arrica, Maria A.; Okazaki, Takao; Bunge, Scott D. European Journal of Organic Chemistry, 2008 , # 36 p. 6093 - 6105

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被引用次数: 3

摘要

Abstract Several regioisomeric acetylnitropyrenes were synthesized from isomeric acetylpyrenes by mild protic nitration. Nitration of 1-acetylpyrene gave the 3-, 6-, and 8-nitro derivatives (with 8-nitro as the major isomer), from which the corresponding carbinols [NO 2- Py-CH (OH) CH 3; Py= pyrene] were synthesized. Isomeric 4-acetylnitropyrenes and their corresponding carbinols were synthesized by starting from hexahydropyrene through ...