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Green Chemistry

Mesoporous poly-melamine-formaldehyde (mPMF)–a highly efficient catalyst for chemoselective acetalization of aldehydes

MX Tan, L Gu, N Li, JY Ying, Y Zhang

文献索引:Tan, Mei Xuan; Gu, Liuqun; Li, Nannan; Ying, Jackie Y.; Zhang, Yugen Green Chemistry, 2013 , vol. 15, # 5 p. 1127 - 1132

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被引用次数: 25

摘要

A mesoporous poly-melamine-formaldehyde polymer with a high surface area, good porosity and a high density of amine and triazine functional groups was investigated as a highly efficient hydrogen-bonding catalyst. This porous organic polymer was found to be highly effective in catalyzing chemoselective acetalization of aldehydes, without the consumption of any dehydrating agents. The turnover frequency of mesoporous poly- ...