A spectroscopic study on the coordination and solution structures of the interaction systems between biperoxidovanadate complexes and the pyrazolylpyridine-like …
In order to understand the substitution effects of pyrazolylpyridine (pzpy) on the coordination reaction equilibria, the interactions between a series of pzpy-like ligands and biperoxidovanadate ([OV (O 2) 2 (D 2 O)]−/[OV (O 2) 2 (HOD)]−, abbrv. bpV) have been explored using a combination of multinuclear (1 H, 13 C, and 51 V) magnetic resonance, heteronuclear single quantum coherence (HSQC), and variable temperature NMR in a ...
