Regio??and Stereospecific Cleavage of Stannyloxiranes with Lithium Diphenylphosphide

AM González??Nogal, P Cuadrado…

文献索引：Gonzalez-Nogal, Ana M.; Cuadrado, Purification; Sarmentero, M. Angeles European Journal of Organic Chemistry, 2009 , # 6 p. 850 - 859

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被引用次数: 10

摘要

Abstract Unsubstituted or C-substituted stannyloxiranes reactedstereospecifically with lithium diphenylphosphide to give either β-hydroxyphosphane oxides resulting from α- opening or β-phosphanyl ketones by β-opening. Furthermore, the reactivities of distannyloxiranes depend on their configurations. The cis isomers afforded the corresponding α, β-diphosphanyl alcohols, while the trans isomers were shown to be ...