Tetrahedron

New and efficient routes for the synthesis of murrayaquinone A and murrayanine

SM Bhosale, AA Momin, RS Kusurkar

文献索引：Bhosale, Shrikar M.; Momin, Aadil A.; Kusurkar, Radhika S. Tetrahedron, 2012 , vol. 68, # 32 p. 6420 - 6426

被引用次数: 5

摘要

Three new routes were established for the synthesis of biologically active murrayaquinone A and a new method was developed for synthesis of murrayanine from the same starting material as 4-hydroxy carbazole. During the synthetic course a few novel observation were recorded, which include two one pot reaction sequences and C–N bond cleavage by sodium cyanoborohydride.

~72%

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~87%

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