Photolysis and Thermolysis of Pyridyl Carbonyl Azide Monolayers on Single??Crystal Platinum

…, K Griffiths, PR Norton, MS Workentin

文献索引：Adkinson, Dana K.; Magri, David C.; Pitters, Jason L.; Griffiths, Keith; Norton, Peter R.; Workentin, Mark S. Photochemistry and Photobiology, 2013 , vol. 89, # 5 p. 1020 - 1028

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摘要

Abstract The photochemical and thermal reactivity of a number of acyl azide-substituted pyridine compounds, namely nicotinyl azide, isonicotinyl azide, picolinyl azide and dinicotinyl azide with investigated as saturated monolayers on a single-crystal Pt (111) surface in an ultrahigh vacuum chamber. Multilayers of the substrates exhibited a maximum rate of desorption at 270 K, above which, stable saturated monolayers formed as ...