Tetrahedron letters

Dissymetrisation de la molecule du glyoxal 1-synthese et reactivite de L'acetoxy-1 triethoxy-1, 2, 2 ethane

…, F Chastrette, R Amouroux, M Chastrette, G Mattioda…

文献索引：Stambouli, A.; Chastrette, F.; Amouroux, R.; Chastrette, M.; Mattioda, G.; Blanc, A. Tetrahedron Letters, 1986 , vol. 27, # 35 p. 4149 - 4152

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被引用次数: 8

摘要

Résumé Acétoxy-1 triéthoxy-1, 2, 2 éthane, a dissymetric derivative of glyoxal, is prepared and reacted with various bases and nucleophiles, as amines, cyanotriméthylsilane, organometallic and WITTIG reagents. Various acetals are obtained, leading to α- fonctionalized aldehydes.