Addition of trichloromethyl radicals to alkenylsilanes

H Sakurai, A Hosomi, M Kumada

文献索引：Sakurai,H. et al. Journal of Organic Chemistry, 1969 , vol. 34, p. 1764 - 1768

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被引用次数: 64

摘要

Dibenzoyl peroxide catalyzed addition of bromotrichloromethane to various types of vinyl- and w-alkenylsilanes have been investigated. Six new addition compounds have been prepared and characterized. It has been found that the reactivity of the double bond in the series of R (CH3) aSiCH= CH2, where R= Me, Et, i-Pr, and t-Bu, t, oward addition of the trichloromethyl radical is governed by the Taft steric factor, E., of R, while the reactivity in ...