Tetrahedron

Synthesis and characterization of alkyl-, halo-and hetero-substituted derivatives of the potent phototoxin α-terthienyl

A Mac Eachern, C Soucy, LC Leitch, JT Arnason…

文献索引：Eachern, Anita Mac; Soucy, Chantal; Leitch, Leonard C.; Arnason, John T.; Morand, Peter Tetrahedron, 1988 , vol. 44, # 9 p. 2403 - 2412

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被引用次数: 68

摘要

A number of derivatives of α-terthienyl were prepared including a series of naturally occurring compounds. A description of the syntheses of some new compounds, including 5- iodo, 5, 5'-diiodo, 5, 5'-diformyl, 5.5'-di-tert butyl, 5,-tert-butyl, 5-tert-butoxy, 5-trimethylsilyl, 5- thiomethyl, 5, 5-dithiomethyl and 5-carboxyl-5-(trimethylsilyl)-2, 2': 5', 2'-terthienyl is also given. An analysis of the 1H NMR data of the derivatives is presented.