The Journal of Organic Chemistry

Group migrations of carbene centers. Pyrolysis of the sodium salts of. alpha.-arylisobutyrophenone tosylhydrazones

JA Landgrebe, AG Kirk

文献索引：Landgrebe,J.A.; Kirk,A.G. Journal of Organic Chemistry, 1967 , vol. 32, p. 3499 - 3506

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被引用次数: 16

摘要

2. H, O+ HC0, H and mass spectral data as well as by elemental analysis. The gemdimethyl group of all three olefins appeared as a singlet at 7 8.20-8.23. With the exception of ala'- dimethylstilbene 3a which was prepared from l-phenylethyl chloride by the method of Kharasch and Kleiman, 4 the other olefinic products which would result from the migration of methyl to the carbene center were conveniently synthesized by the sequence of reactions ...