Synthesis and Self??Assembly of NCN??Pincer Pd??Complex??Bound Norvalines

…, H Seike, T Ogawa, H Kurata, N Yasuda…

文献索引：Ogata, Kazuki; Sasano, Daisuke; Yokoi, Tomoya; Isozaki, Katsuhiro; Yoshida, Ryota; Takenaka, Toshio; Seike, Hirofumi; Ogawa, Tetsuya; Kurata, Hiroki; Yasuda, Nobuhiro; Takaya, Hikaru; Nakamura, Masaharu Chemistry - A European Journal, 2013 , vol. 19, # 37 p. 12356 - 12375

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被引用次数: 4

摘要

Abstract The NCN-pincer Pd-complex-bound norvalines Boc-D/L-[PdCl (dpb)] Nva-OMe (1) were synthesized in multigram quantities. The molecular structure and absolute configuration of 1 were unequivocally determined by single-crystal X-ray structure analysis. The robustness of 1 under acidic/basic conditions provides a wide range of N-/C-terminus convertibility based on the related synthetic transformations. Installation of a variety of ...