Bis-catecholate, bis-dithiocatecholate, and tetraalkoxy diborane (4) compounds: Aspects of synthesis and electronic structure

…, P Nguyen, G Lesley, TB Marder, JA Ashmore…

文献索引：Lawlor, Fiona J.; Norman, Nicholas C.; Pickett, Nigel L.; Robins, Edward G.; Nguyen, Paul; Lesley, Gerry; Marder, Todd B.; Ashmore, Jennifer A.; Green, Jennifer C. Inorganic Chemistry, 1998 , vol. 37, # 20 p. 5282 - 5288

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被引用次数: 55

摘要

The synthesis and charaterization of a series of diborane (4) compounds, such as B2 (1, 2- O2C6H4) 2 (3), B2 (1, 2-S2C6H4) 2 (13), and B2 (OCH2CMe2CH2O) 2 (11), and several ring-substituted derivatives of the catecholate and dithiocatecholate compounds are described along with photoelectron spectroscopic studies on 3, 11, B2 (OCMe2CMe2O) 2 (12), and B2 (NMe2) 4 (1). Several intermediates, impurities, and side reactions have ...