Synthesis and multinuclear NMR studies of 3-aminopropyl (aryl) chalcogenides, NH 2 CH 2 CH 2 CH 2 EAr (E= Se, Te), and their complexes with Pt (II) and Pd (II)
A Khanna, A Bala, BL Khandelwal
文献索引:Khanna, Anju; Bala, Anju; Khandelwal, B. L. Journal of Organometallic Chemistry, 1995 , vol. 494, # 12 p. 199 - 204
The asymmetric ligands, 3-aminopropyl (aryl) tellurides (1a, lb)[Ar= Ph (a); C6H4-OMe (b)] and 3-aminopropyl (phenyl) selenide (2) and their complexes with platinum (II) and palladium (II), viz.[PtCl2 (1a, lb)](3, 4),[PtCl2 (2)](5),[PdCl2 (1a, 1b)](6, 7),[PdCl2 (2)](8),[(Me) ClPd (1b)](9) and [(Me) ClPd (1b) 2](10) have been made and characterized. Complexes 3– 8, have square planar geometry around the metal (Pd or Pt) with the (Te, N)-or (Se, N)- ...