Organic letters

Supramolecular multicomponent self-assembly of shape-adaptive nanoprisms: wrapping up C60 with three porphyrin units

M Schmittel, B He, P Mal

文献索引：Schmittel, Michael; He, Bice; Mal, Prasenjit Organic Letters, 2008 , vol. 10, # 12 p. 2513 - 2516

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被引用次数: 75

摘要

Self-assembly of a C 3 v symmetric trisphenanthroline and linear bisterpyridines in the presence of Cu+ did not furnish the expected supramolecular nanoprisms in quantitative yield. With an accurately sized tripyridine as a stabilizing template, the nanoprism formed exclusively. Furthermore, an adaptive constriction of the nanoprism was seen with C60 as template: as a result of the smaller size of C60 the nanoframework wrapped up around the ...