Specific features of catalytic hydrosilylation in siloxane systems in the presence of sulfoxide-containing platinum (II) complexes

…, VA Ol'Sheev, VN Spevak, NK Skvortsov

文献索引：Vekki, D. A. de; Ol'sheev, V. A.; Spevak, V. N.; Skvortsov, N. K. Russian Journal of General Chemistry, 2001 , vol. 71, # 12 p. 1912 - 1923 Zhurnal Obshchei Khimii, 2001 , vol. 71, # 12 p. 2017 - 2030

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被引用次数: 10

摘要

Abstract The rate of addition of MeSiH (OSiMe 3) 2, Me 2 SiHOSiMe 3, and (Me 2 SiH) 2 O to vinylsiloxanes ViMeSi (OSiMe 3) 2, ViMe 2 SiOSiMe 3, and (ViMe 2 Si) 2 O in the presence of square-planar platinum complexes [Pt (LL') X 2](where L and L'are neutral ligands, and X is an anionic ligand) decreases in the following series of L and L': Ph 3 PS> MeS (O) Tol-p> MeCOD> CH 2 ÍCH 2≈ COD> Et 2 SO> Et 2 S> Me 2 SO≫ 2-aminopyridine> Py> 2- ...