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Inorganica Chimica Acta

Electron transfer studies on Cu (II) complexes bearing phenoxy-pincer ligands

A Klein, K Butsch, J Neudörfl

文献索引:Klein, Axel; Butsch, Katharina; Neudoerfl, Joerg Inorganica Chimica Acta, 2010 , vol. 363, # 13 p. 3282 - 3290

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被引用次数: 9

摘要

Oxido-pincer ligands with phenolate-groups [2, 6-bis (2-methoxyphenyl) pyridine (LOMe2), 2, 6-bis (2-hydroxyphenyl)-pyridine (LOH2), 2, 6-bis-(2, 4-dimethoxyphenyl)-pyridine (LOMe4)] coordinate to CuII forming binuclear complexes which can be easily and reliably converted into mononuclear species. Their physical properties were analysed using EPR, optical spectroscopy and (spectro-) electrochemical methods. The results were compared ...