Journal of the Chemical Society C: Organic

Organoboron compounds. Part VI. Photochemical reactions of aryl and alkyl halides with boron halides

RA Bowie, OC Musgrave

文献索引：Bowie,R.A.; Musgrave,O.C. Journal of the Chemical Society [Section] C: Organic, 1966 , p. 566 - 571

全文：HTML全文

被引用次数: 10

摘要

The photolysis of aryl iodides in the presence of boron halides results in the formation of arylboron dihalides and diarylboron halides by free-radical substitution reactions. Hydrolysis of the products gives the corresponding boronic and borinic acids. Alkyl iodides and di-iodo- compounds behave in a similar manner. The photolysis and subsequent hydrolysis of mixtures of bromo-or chloro-benzene with boron tribromide also affords boronic acids; the ...