Tetrahedron

Thermal rearrangement of xanthates to dithiolcarbonates—I

T Taguchi, M Nakao

文献索引：Taguchi,T.; Nakao,M. Tetrahedron, 1962 , vol. 18, p. 245 - 255

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被引用次数: 25

摘要

During the pyrolysis of β-dialkylaminoalkyl S-methyl xanthates, dl-trans-2- dimethylaminocyclohexyl S-methyl xanthalate was rearranged without elimination to the corresponding dithiolcarbonate while the cis isomer suffered over-all elimination. It has been suggested that the dimethylamino group attached to the carbon carrying the xanthate group induces the rearrangement. Other examples studied support this mechanism. 2- ...