Synthesis, structure, electrochemistry and ROMP-activity of new ferrocenyl analog of Grubbs' metathesis catalyst

…, B Mondal, VG Puranik, PP Wadgaonkar…

文献索引：Maishal, Tarun K.; Mondal, Biplab; Puranik, Vedavati G.; Wadgaonkar, Prakash P.; Lahiri, Goutam Kumar; Sarkar, Amitabha Journal of Organometallic Chemistry, 2005 , vol. 690, # 4 p. 1018 - 1027

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被引用次数: 18

摘要

Treatment of [(PCy3) 2Cl2RuCH–Ph](I) with vinylferrocene 1 and 1-ferrocenyl-1, 3- butadiene 2 yielded solid products. These new complexes were characterized by 1H NMR, 31P NMR and 13C NMR spectroscopy. X-ray crystal structures of both the complexes have been solved. The crystal structure of II confirmed the assigned structure and revealed existence of two sets of intermolecular C–H–Cl (M) type interactions, viz.(Ru) Cl–H–C ( ...