Organofluorine compounds and fluorinating agents Part 17: Sonochemical-forced preparation of perfluoroalkanals and their use for non-conventional acetalations of …

…, D Peters, C Zur, M Frank, R Miethchen

文献索引：Miller, Alexey O.; Peters, Dietmar; Zur, Cornelia; Frank, Michael; Miethchen, Ralf Journal of Fluorine Chemistry, 1997 , vol. 82, # 1 p. 33 - 38

全文：HTML全文

被引用次数: 16

摘要

The homologous 1-iodo-perfluoroalkanes 1a-1c and α, ω-dibromo-perfluoroalkanes 4a, 4b were carbonylated with DMF in the presence of Al/SnCl2 Al/PbBr2 under sonication in a short reaction time. The hydrated aldehydes 2a-2c and 5a, 5b respectively were obtained in good yields allowing dehydration to 3a-3c and 6a, 6b. Some of the fluorinated aldehydes were selected as substrates in a Wittig-Horner olefination assisted by ultrasound and in ...