Journal of organometallic chemistry

Facile hydroboration of (Z)-1-trimethylsilyl-1-alkenes with dichloroborane–dioxane complex: An easy access to gem-dimetalloalkanes containing boron and silicon

NG Bhat, MA Villanueva

文献索引：Bhat, Narayan G.; Villanueva, Mary A. Journal of Organometallic Chemistry, 2006 , vol. 691, # 6 p. 1298 - 1300

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被引用次数: 1

摘要

(Z)-1-trimethylsilyl-1-alkenes easily prepared by the hydroboration of the corresponding 1- trimethylsilyl-1-alkynes followed by protonolysis with acetic acid, readily react with dichloroborane–dioxane complex in dichloromethane for 6h. The resulting solution is then treated with 1, 3-propane diol in dichloromethane at 0° C for half an hour to provide the corresponding gem-dimetalloalkanes containing boron and silicon. These α- ...