… structure of [OC-6-22-(R*, R*)]-(±)-dichloro {1, 2-bis [(2-dimethylphosphinophenyl) methylphosphino] benzene-P, P′, P′′, P′′′} cobalt (III) hexafluorophosphate

…, R Doyle, DCR Hockless, G Salem, AC Willis

文献索引：Chatterjee, Swarup; Doyle, Roy; Hockless, David C. R.; Salem, Geoffrey; Willis, Anthony C. Journal of the Chemical Society, Dalton Transactions, 2000 , # 12 p. 1829 - 1830

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摘要

Reaction of (±)-(2-chlorophenyl)(2-dimethylphosphinophenyl) methylphosphine with sodium (2-dimethylphosphinophenyl) methylphosphide is completely stereoselective giving (R*, R*)- 1, 2-bis [(2-dimethylphosphinophenyl) methylphosphino] benzene,(R*, R*)-1; as confirmed by a crystal structure determination of cis-α-[CoCl2 {(R*, R*)-1}] PF6.