Organometallics

Synthesis and reactions of KGa (CH2SiMe3) 2H2 and an attempted preparation of Ga (CH2SiMe3) 2H. The search for a reductive elimination reaction

OT Beachley Jr, RB Hallock

文献索引：Beachley, O. T.; Hallock, R. B. Organometallics, 1984 , vol. 3, p. 199 - 201

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被引用次数: 10

摘要

The new compound KGa (CH2SiMeJ2H2 has been prepared from Ga (CH2SiMe3) zBr and excess KH and fully characterized by analysis and'H NMR and IR spectral data. The pure compound is thermally stable below 200" C. Reaction of KGa (CH2SiMeJzH2 with Ga (CH2SiMeJzBr in benzene solution leads to the formation of Ga (CHzSiMe3) zH, which readily decomposes at room temperature to gallium metal, Hz, and Ga (CH2SiMe& The ...