Journal of organometallic chemistry

Allylchlorotins as allylating agents of acyl chlorides

A Gambaro, V Peruzzo, D Marton

文献索引：Gambaro, Alessandro; Peruzzo, Valerio; Marton, Daniele Journal of Organometallic Chemistry, 1983 , vol. 258, # 3 p. 291 - 296

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被引用次数: 6

摘要

Abstract Allylchlorotins of the type R 3-n AllSnCl n (R alkyl or All; All CH 2 CHCH 2 or cis/trans-CH 3 CH CHCH 2, n 1–3) undergo uncatalyzed coupling with acyl chlorides under mild conditions. This reaction as well as the corresponding addition reaction to ketones are much faster when Cl is replaced by NCS group in the organotin derivative.

~92%

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~84%

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~82%

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~77%

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~67%

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~55%

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~49%

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