Chinese Chemical Letters

Tri (t-butyl) phosphine-assisted selective hydrosilylation of terminal alkynes

W Wu, XY Zhang, SX Kang, YM Gao

文献索引：Wu, Wei; Zhang, Xiao Yun; Kang, Shou Xing; Gao, Yan Min Chinese Chemical Letters, 2010 , vol. 21, # 3 p. 312 - 316

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被引用次数: 10

摘要

A highly efficient and regio-/stereoselective method of hydrosilylating terminal alkynes was developed using Pt (DVDS)-tri (t-butyl) phosphine catalyst system at room temperature. Trans-products or alpha-products were obtained almost exclusively depending on the alkynes and silanes employed.