Chemistry Letters

Palladium assisted N-methyl activation of p-substituted N, N-dimethylanilines.

T Sakakibara, T Hamakawa

文献索引：Sakakibara, Tsutomu; Hamakawa, Tomoko Chemistry Letters, 1982 , p. 1823 - 1824

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摘要

Intermediates in the reaction of N, N-dimethylanilines with palladium (II) acetate were trapped by acetate ion or oxygen to give N-methyloxygenated and demethylated products, while the trapping by other anilines gave homo-and cross-coupling cyclodimers. The reactions proceed via radical cation formation induced by the palladium salt.